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Projects / Programmes
Oxomolybdenum(V)clusters with pyridne and its alkylsubstituted derivates
Research activity
| Code | Science | Field | Subfield |
|---|---|---|---|
| 1.04.03 | Natural sciences and mathematics | Chemistry | Inorganic chemistry |
| Code | Science | Field |
|---|---|---|
| P003 | Natural sciences and mathematics | Chemistry |
| P360 | Natural sciences and mathematics | Inorganic chemistry |
Keywords
oxomolybdenum(V)clusters, pryidine, structures
Evaluation
(metodology)
Citations
Citations for bibliographic records in COBIB.SI that are linked to records in citation databases
Organisations (1) , Researchers (1)
0103 University of Ljubljana, Faculty of Chemistry and Chemical Technology
| no. | Code | Name and surname | Research area | Role | Period | No. of publicationsNo. of publications |
|---|---|---|---|---|---|---|
| 1. | 12276 | Chemistry | Head | 1999 - 2001 | 317 |
Abstract
Pentachlorooxomolybdate(V) reacts with the mixture of mthanol and pyridine or its alkylsubtiuted derivative to different neutral oxomolybdenum(V) clusters which all contain dimeric Mo2O4 2+ units. The dimer is a basic building unit in the formation of poynuclear clusters. The mechanism of substitutions within the monomeric ŠMoOCl5Ć2-, as wellas the formation of dimeric units and their fusion into larger aggregates, is unknown and so is the role of the factors which severely affect the reaction route. The main aim of the work is to investigate this reaction.